Article View: sci.bio
Article #543Re: Omega-3 fatty acids
From: Larry Lippman
Date: Sun, 03 Dec 1989 05:20
Date: Sun, 03 Dec 1989 05:20
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2136 bytes
In article <25773343.1707@rpi.edu>, jdh@pawl.rpi.edu (Joseph Herrenkohl) writes:
> The symbol omega refers to the position of a double bond in unsaturated
> fatty acids. Usually the numbering scheme is based on the carboxyl group
> and the position(s) of the double bond(s) are indicated by the superscript
> delta. However an alternative (archaic?) scheme numbers from the terminal
> methyl carbon - the position is then indicated by omega. For example,
> linoleic acid is (delta)9,12-octadecadienoic acid or (omega)6,9-
> octadecadienoic acid.
Oh, great - another scheme for chemical nomenclature. :-)
Pardon me for a moment while I air a pet gripe. As far as I know,
fatty acids haven't changed in the past 20 years since I've been out of
college - so why should the nomenclature change?
As I learned it, linoleic acid was alternatively referred to by the
designation 9,12-octadecadienoic acid. Period. No delta in front of the
9,12 and no alternative omega scheme. As a point of comparison, linolenic
acid (three double carbon bonds) is 9,12,15-octadecatrienoic acid. Now,
if one wanted to be a IUPAC purist, one would merely write these fatty acids
as cis,cis-9,12-octadecadienoic acid or cis,cis,cis-9,12,15-octadecatrienoic
acid.
What could be *simpler*?
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Path: arc1-ca.pugleaf.net!utzoo!utgpu!jarvis.csri.toronto.edu!mailrus!purdue!tut.cis.ohio-state.edu!zaphod.mps.ohio-state.edu!sunybcs!kitty!larry From: larry@kitty.UUCP (Larry Lippman) Newsgroups: sci.bio Subject: Re: Omega-3 fatty acids Summary: YASCN (Yet Another Scheme for Chemical Nomenclature) Keywords: unsaturated fatty acids Message-ID: <3534@kitty.UUCP> Date: 3 Dec 89 05:20:29 GMT References: <859@wrgate.WR.TEK.COM> <3531@kitty.UUCP> <25773343.1707@rpi.edu> Organization: Recognition Research Corp., Clarence, NY Lines: 29