Article View: sci.electronics
Article #3177Re: Air-Aluminum Battery/Fuel-cell
From: Duke McMullan n5gax
Date: Sun, 24 Sep 1989 02:42
Date: Sun, 24 Sep 1989 02:42
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In article <21000041@m.cs.uiuc.edu> estell@m.cs.uiuc.edu writes:
> "The ALUPOWER battery cell uses a special Aluminum alloy as an anode
>and Air as a cathode. The electrolyte is Salt Water." The Al reacts with
>H2O to produce Al(OH)3; the excess of electrons at the anode and O2 from the
>air reacts with H2O to form OH- , depleting electrons from the cathode.
>
>The "special Al alloy" obviously contains some sort of catalyst to speed up
>the reaction between the O2 and H2O, but I don't know what it is that
>they added.
Hey, I'd sure like to know. I've tried replacing the anodes with vanilla
aluminum alloys, and the cell current drops considerably. (I've never measured
the open-circuit voltage -- I ought to....)
I'm messing with this cell to see if I can come up with something that's useful
as a power source for caving. So far, the Al-O2 battery looks good chemically
and electrically, but hasn't the physical durability to stand up to this sort
of service.
Imagine it: you lose your balance and land on a large rock. No injury, but
the battery cathode diaphram got punctured. Oops.
Or: you're crawling down a lemon-squeezer passage -- the sort where you have
to exhale to move forward -- and the thing dips sharply downward. To go down,
you have to invert that battery almost all the way. There isn't any way you
can turn around, not even enough room to take the battery off your belt. Why
does your belly seem wet? Because the electrolyte has drained out of the
battery. Oops, again.
Someday, perhaps. As it stands, I'm not much impressed by this particular
cell, physically. A shame, 'tis.
Minding knows inquire to want,
d
-- Generic Apophthegmatic Statement --
Duke McMullan n5gax nss13429r phon505-255-4642 ee5391aa@hydra.unm.edu
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<593@ariel.unm.edu>Path:
arc1-ca.pugleaf.net!utzoo!attcan!uunet!ginosko!uakari.primate.wisc.edu!uwm.edu!mailrus!ncar!unmvax!ariel!hydra.unm.edu!ee5391aaShow Full Headers
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Path: arc1-ca.pugleaf.net!utzoo!attcan!uunet!ginosko!uakari.primate.wisc.edu!uwm.edu!mailrus!ncar!unmvax!ariel!hydra.unm.edu!ee5391aa From: ee5391aa@hydra.unm.edu (Duke McMullan n5gax) Newsgroups: sci.electronics,sci.chem Subject: Re: Air-Aluminum Battery/Fuel-cell Keywords: Primary cell, odd chemistries Message-ID: <593@ariel.unm.edu> Date: 24 Sep 89 02:42:03 GMT Sender: news@ariel.unm.edu Reply-To: ee5391aa@hydra.unm.edu (Duke McMullan n5gax) Organization: University of New Mexico, Albuquerque, NM Lines: 39