Article View: sci.nanotech
Article #821Nanolithography
From: Nick Szabo
Date: Sat, 21 Nov 1992 02:00
Date: Sat, 21 Nov 1992 02:00
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7005 bytes
Tim May has described nanolithography that uses linear arrays of 1e4-1e5 AFM's that would scan a chip and fill in detail to 10 nm resolution or better. The AFM tips could either expose a resist, directly etch or directly deposit material. Nanolithography seems to me a major breakthrough in the road towards Drexler's vision of nanotechnology. What follows includes further nanolith techniques that I have brainstormed. A nearer-term use of AFMs or STMs that requires only writing and reading a few atoms is to create an atomic-scale vernier that would be used for alignment of more traditional lithographic pattern transfer techniques such as ions, e-beams, x-rays, etc. By using STM alignment and decreasing the distance from the radiation source to the wafer surface, many traditional techniques still have room for improvement to below 100 nm. A field of great interest to nanotech is protein engineering: Brownian assembled proteins, structures made out of DNA, self-replicating systems vastly different from the natural DNA/RNA/ribosome system, etc. Despite the modelling difficulties, the shear momentum in protein engineering is such that we may see many complex and useful protein and other organic systems emerging during the next decade. I suggest a class of such systems which I call _nanoresists_. These would be proteins and other molecules that, upon specific stimulation, assemble into geometric two-dimensional shapes such as line segments, circles, donuts, squares, hexagons, meshes, etc. A primitive nanoresist would form this shape based on a simple Brownian assembly process upon being impinged with radiation. Note that the radiation delivers only a process-start signal; the pattern emerges from the protein or polymer self-assembly. Alternatively, prepatterned nanoresist films can be placed on the wafer by STMs or molecular-tip AFMs. More advanced nanoresists might include the following capabilities: * Shape formed from a code based on radiation wavelength and start/stop pulses; it might be formed from rhodopsin or other dye molecules that transmit excitons to a protein-assembling process. * Shape formed by a short DNA code, which has been created by recombinant techniques and mass-produced by the polymerase chain reaction (PCR). The DNA would form themselves into specific shapes, rather than going through the DNA-mRNA-ribosome-protein translation process. * Specific 2D patterns produced by actual organisms distributed in a controlled manner on the substrate. Some existing creatures can form sophisticated hexagonal, spiral, and capillary structures; via genetic engineering we might be able to make an even wider variety of patterns. In each case the finished resist byproducts are etched away, leaving the skeleton which is the actual 2D resist pattern. The resist can be either positive or negative; that is it can serve to protect the substrate from further deposition or from etching. The etching or deposition process becomes the limiting factor, since nanoresists themselves might achieive resolutions below 1 nm. Small-scale lithography not only improves the feature density of existing devices but also makes possible a wide variety of new devices that take advantage of quantum effects: glowing nanopore silicon, quantum dots and wells, tunneling magnets, squeezed lasers, etc. Good yields are now being achieved in the deposition of diamond film, by seeding a silicon surface with diamond seeds and then growing the diamond crystals epitaxially on those seeds from hot hydrogen and methane. The diamond can also be etched by nitrogen dioxide, and does not suffer the crystal damage that often results from etching with fast atoms. Thus, diamond etching has a better prospect of matching the resolution of nanoresists than traditional silicon etching with oxygen. Diamond lithography may soon havae the following capabilities: * Produce diamond-based ICs, vacuum tubes, and flat-screen display elements. * Produce thousands of AFM cantilevers, tips, and control systems on one wafer. These AFM's can then be used to lithograph further wafers, as described by May. * Produce many diamond mechanical parts similar to those described in Drexler's _Nanosystems_, but via lithography instead of Drexler's molecular-machine assembly. The latter process is the most speculative, but ultimately the most fruitful. Using nanoresists, and assuming that etching or deposition can be controlled to resolutions approaching single atomic layers, we might create billions of mechanical diamond parts, of a wide variety, on a single wafer. Many of these parts would be flawed on an atomic scale, but these could be eliminated by the following process: First, errors produced by consistent differences between the nanoresist shape and the desired part shape might be eliminated by bathing the parts in a solution containing enzymes that attack and destroy the specific atomic site errors. Second, using advanced AFM or STM arrays, create an atomic-scale mesh. The arrays don't have to be efficient, we only need to do it a few times to debug the process, like making a mask. But they do need to produce a series of holes perfect on the atomic scale. The mesh comes in three varieties. These contain 2D holes in the shape of the side view, top view and plan view of the 3D part. Once we have lithographed the billions of parts, we sort them through the meshes on a tilted, vibrating table. Only the perfectly made parts get through; the others get vibrated away into the recycling bin. Even if we have an error rate of 99.9% on 1,000-atom parts, we can get a million useful parts per billion-part wafer. Three meshes can serve to error-check trillions of parts. Note that while nanolithography can greatly extend the capability of nanotechnology, and help bridge the gap between current technology and Drexler's self-replicating factories, it in no way diminishes the importance of Drexler's mechanical-assembly approach. Rather, the technologies are symbiotic: lithography makes the parts, and Drexler's machines can then assemble them together in a variety of ways. With nanolithography, early Drexler machines can concentrate on assembly and leave the more complex diamondoid mechanosynthesis to later. ref: K. Eric Drexler, _Nanosystems_, John Wiley & Sons 1992 Geis & Angus, "Diamond Film Semiconductors", Sci. Am. 10/92 Tim May, personal communication
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Path: arc1-ca.pugleaf.net!sparky!uunet!cs.utexas.edu!sun-barr!rutgers!igor.rutgers.edu!planchet.rutgers.edu!nanotech From: szabo@techbook.com (Nick Szabo) Newsgroups: sci.nanotech Subject: Nanolithography Message-ID: <Nov.20.21.00.13.1992.26419@planchet.rutgers.edu> Date: 21 Nov 92 02:00:15 GMT Sender: nanotech@planchet.rutgers.edu Lines: 123 Approved: nanotech@aramis.rutgers.edu