Article View: sci.nanotech
Article #831Mass molecular positioning with fabricated catalyst
From: Nick Szabo
Date: Tue, 05 Jan 1993 03:44
Date: Tue, 05 Jan 1993 03:44
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1247 bytes
Lithography has been used to fabricate a series of catalytic towers on a chip (Science 20 Nov. '92, pg. 1337). The towers consist of alternating layers of SiO2 4.1 nm thick and Ni 2-10 nm thick. The deposition process achieves nearly one atom thickness control for both SiO2 and Ni. Previously it was thought that positioning in three dimensions was required for good catalysis, but this catalyst's nanoscale 1-d surface force reagants into the proper binding pattern. It achieved six times the reaction rate of traditional cluster catalysts on the hydrogenolysis of ethane to methane, C2H6 + H2 --> 2CH4. The thickness of the nickel and silicon dioxide layers can be varied to match the size of molecules to be reacted. Nick Szabo szabo@techbook.com
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<Jan.4.22.44.22.1993.8173@planchet.rutgers.edu>Path:
arc1-ca.pugleaf.net!sparky!uunet!zaphod.mps.ohio-state.edu!howland.reston.ans.net!usc!cs.utexas.edu!swrinde!gatech!rutgers!igor.rutgers.edu!planchet.rutgers.edu!nanotechShow Full Headers
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Path: arc1-ca.pugleaf.net!sparky!uunet!zaphod.mps.ohio-state.edu!howland.reston.ans.net!usc!cs.utexas.edu!swrinde!gatech!rutgers!igor.rutgers.edu!planchet.rutgers.edu!nanotech From: szabo@techbook.com (Nick Szabo) Newsgroups: sci.nanotech Subject: Mass molecular positioning with fabricated catalyst Message-ID: <Jan.4.22.44.22.1993.8173@planchet.rutgers.edu> Date: 5 Jan 93 03:44:23 GMT Sender: nanotech@planchet.rutgers.edu Lines: 17 Approved: nanotech@aramis.rutgers.edu