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Article #1176

cluster-integrals

#1176
From: meuwly
Date: Tue, 14 Apr 1992 13:35
33 lines
1218 bytes
hello there,
i'm looking for an evaluation of cluster-integrals. i need it for the
partition-function of a real gas in the mayer-cluster-expansion.

i know that there must be an explicit formula for at least the 
first 4 cluster-integrals. the first 3 ones are

 b  = 1
  1

          infinity
     2*Pi  /                    2
 b = ----  | ((exp(-V(r)/kT)-1)r  dr
  2  L^3   /
           0

                infinity
       2     1   /  3    3
 b = 2b  +  ---- | d r  d r   f  f  f
  3    2    6L^6 /    12   13  12 13 23
                 0


L is the de broglie-wavelength and f   are the [ik] clusters of the molecules
                                    ik

there must be a phd-thesis by harrison: john hopkins-university 1938 on that
subject whee the first 4 clusterintegrals are computed. who knows something
about this subject?



thanks for your help    markus
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Path: arc1-ca.pugleaf.net!sparky!uunet!think.com!mips!darwin.sura.net!Sirius.dfn.de!chx400!urz.unibas.ch!meuwly
From: meuwly@urz.unibas.ch
Newsgroups: sci.physics
Subject: cluster-integrals
Message-ID: <1992Apr14.143542.14123@urz.unibas.ch>
Date: 14 Apr 92 14:35:42 MET
Organization: University of Basel, Switzerland
Lines: 33