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Article #4296Question: How to remove oxide from gallium?
From: Ermanno Borra
Date: Thu, 01 Oct 1992 19:58
Date: Thu, 01 Oct 1992 19:58
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1863 bytes
I wonder whether somebody can suggest solutions to my problem. I pour either liquid gallium or a Ga-In eutectic in a container, and find that the surface (several feet across) is covered with a thick layer of oxide scum. The problem occurs during stirring, that occurs just when I pour Ga After pouring, I do not stir the liquid again. I would like to get rid of the opaque oxide scum and get a shiny optical quality surface. Although it is in principle possible to work in an inert atmosphere and avoid the oxide, it is difficult to do so in practice, because of our setup. I know that, in an oxygen atmosphere, an oxide layer forms instantly but this is OK since the oxide layer that forms on an undisturbed surface is very thin and protects the Ga below from oxidation (like it does with Al). My real problem occurs at the moment of pouring since the liquid is stirred and we get too much thick messy oxide. Ideally, I would like to remove the oxide with chemical means, get a clean Ga surface that can be oxidized with the very thin layer of oxide that naturally forms on an undisturbed surface. I have tried to expose the oxide to HCl vapors. The surface becomes more reflective but its quality is not good enough for my application (using it as a an optical mirror). If you have a suggestion, please email at borra@phy.ulaval.ca Thanks, E.F. Borra
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Path: arc1-ca.pugleaf.net!sparky!uunet!utcsri!bonnie.concordia.ca!cerberus.ulaval.ca!astro!borra From: borra@astro.phy.ulaval.ca (Ermanno Borra) Newsgroups: sci.physics,sci.engr,sci.chem,sci.materials Subject: Question: How to remove oxide from gallium? Message-ID: <1992Oct1.195841.3385@cerberus.ulaval.ca> Date: 1 Oct 92 19:58:41 GMT Sender: news@cerberus.ulaval.ca Organization: Universite Laval, Ste-Foy, Quebec (Canada) Lines: 26 Originator: borra@astro