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Article #4867Re: ferromagnetism: the QM basis
From: Michael Weiss
Date: Thu, 12 Nov 1992 20:01
Date: Thu, 12 Nov 1992 20:01
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1766 bytes
Thank you for the explanation. I think I'm beginning to get a glimmer.
Let me try out my own rewording for size:
1) The exchange energy is not simply another name for the Pauli exclusion
principle. Rather, it is correction to the classical calculation for
the electrostatic energy, and arises from the antisymmetry
properties of the wave function for an ensemble of electrons.
Coulomb's formula applied to an antisymmetric distribution yields
(classical electrostatic energy) + (exchange energy) + lower order terms.
(Would it be correct to say it is due to the need to treat an
ensemble of electrons with Fermi-Dirac statistics rather than Boltzman
statistics?)
2) The exchange energy affects the way electrons fill up energy levels in a
solid, again modifying classical expectations. For iron, it turns out
the minimum energy configuration is with the electon "gas" having aligned
spins, and the bound electrons having spins aligned too, but aligned
opposite to the free electrons.
3) There is no simple qualitative explanation of why iron should have this
sort of minimum energy state, while copper, for instance, doesn't.
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Path: arc1-ca.pugleaf.net!sparky!uunet!know!mips2!cass.ma02.bull.com!think.com!news!columbus From: columbus@strident.think.com (Michael Weiss) Newsgroups: sci.physics Subject: Re: ferromagnetism: the QM basis Message-ID: <COLUMBUS.92Nov12150158@strident.think.com> Date: 12 Nov 92 20:01:58 GMT References: <COLUMBUS.92Nov11135327@strident.think.com> <BxL9xq.EHJ@wsrcc.com> Organization: Thinking Machines Corporation, Cambridge MA, USA Lines: 23 NNTP-Posting-Host: strident.think.com In-reply-to: alison@wsrcc.com's message of Thu, 12 Nov 1992 05:58:37 GMT