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Article #5017Re: Metals in liquid Nitrogen !!
From: Cameron Randale Bass
Date: Fri, 11 Dec 1992 21:29
Date: Fri, 11 Dec 1992 21:29
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In article <1992Dec11.200754.6398@magnus.acs.ohio-state.edu> kpearce@magnus.acs.ohio-state.edu (BULLDAWG) writes:
>In article <1992Dec11.192622.6719@murdoch.acc.Virginia.EDU> crb7q@kelvin.seas.Virginia.EDU (Cameron Randale Bass) writes:
>>In article <1992Dec11.171454.3158@magnus.acs.ohio-state.edu> kpearce@magnus.acs.ohio-state.edu (BULLDAWG) writes:
>>
>>[discussion of boiling in nitrogen deleted]
>>>
>>>But at this point, the metal makes a phase transition from one kind of
>>>metal crystal to another (bcc to alpha). Whenever a substance under goes
>>>a phase trnsition it gives up heat. So what was happining was that the
>>>metal was bubbling away as it cooled down giving up heat in a straight-
>>>forward way and then at a centain temperature, the metal says "hey, I'm in the
>>>wrong shape, and I have too much energy" and then gives up that excess energy
>>>_in_addition_ to the heat energy it was giving up to begin with and then
>>>as soon as it makes the phase transition, the copper goes to cooling down as
>>>before (the bubbles slow down).
>>
>> So all metals have discrete phase transitions near the boiling point of
>> nitrogen? And these phase transitions involve increased cooling
>> /increased heat transfer?
>
>Of course not.
Check the numbers on such phase transitions. Further, I think you'll find
that they are readily taken care of by the relevant specific heat.
You'll also find that this has precious little to do with the
phenomenon.
>>
>> I think you'll find that it is just changes in the heat
>> transfer characteristics of the metal/fluid interface down near
>> the boiling incipience point that are the real cause.
>>
>> See my earlier posting for details.
>>
>
>I saw the earlier post. The data shown is over a range of temperatures.
>All LN2 that is found in an open dewar will be 77K. Refering to his chart,
>the LN2 should be boiling furiously (and is not, I just took a look to
>make sure). The data that you show in your chart just doesn't apply to this
>process (since it is all taking place at 77K).
No, you misread the graph. The x-axis is surface superheat (T_wall
- T_bulk, or in this case T_coin-T_bulk), the difference in
temperature between the coin and the bath. When that goes to zero,
the coin goes to 77K. Then there is no boiling. And the graph
applies to *all* saturated pool boiling from a surface in newtonian
fluids. You'll note that there are *no* value notations on the axes,
though I did give representative superheats for nitrogen in a
specific situation. Even misreading the graph, how did you decide
where 77K was? It could have been in the convective region.
In any case, boiling is driven by delta T in this case.
As far as the statement that 'all LN2 that is found in an open dewar
will be 77K', I think you'll find that is a sweeping overgeneralization.
You could easily put 72K LN2 in an open dewar. Transients can
be as small as you wish the dewar to be large.
dale bass
--
C. R. Bass crb7q@virginia.edu
Department of Mechanical,
Aerospace and Nuclear Engineering
University of Virginia (804) 924-7926
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<1992Dec11.171454.3158@magnus.acs.ohio-state.edu> <1992Dec11.192622.6719@murdoch.acc.Virginia.EDU> <1992Dec11.200754.6398@magnus.acs.ohio-state.edu>Show Full Headers
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Newsgroups: sci.physics Path: arc1-ca.pugleaf.net!sparky!uunet!wupost!cs.utexas.edu!sdd.hp.com!caen!uvaarpa!murdoch!kelvin.seas.Virginia.EDU!crb7q From: crb7q@kelvin.seas.Virginia.EDU (Cameron Randale Bass) Subject: Re: Metals in liquid Nitrogen !! Message-ID: <1992Dec11.212920.9688@murdoch.acc.Virginia.EDU> Sender: usenet@murdoch.acc.Virginia.EDU Organization: University of Virginia References: <1992Dec11.171454.3158@magnus.acs.ohio-state.edu> <1992Dec11.192622.6719@murdoch.acc.Virginia.EDU> <1992Dec11.200754.6398@magnus.acs.ohio-state.edu> Date: Fri, 11 Dec 1992 21:29:20 GMT Lines: 64